Cargando…

Frustrated Lewis Pair Mediated 1,2‐Hydrocarbation of Alkynes

Frustrated Lewis pair (FLP) chemistry enables a rare example of alkyne 1,2‐hydrocarbation with N‐methylacridinium salts as the carbon Lewis acid. This 1,2‐hydrocarbation process does not proceed through a concerted mechanism as in alkyne syn‐hydroboration, or through an intramolecular 1,3‐hydride mi...

Descripción completa

Detalles Bibliográficos
Autores principales:	Fasano, Valerio, Curless, Liam D., Radcliffe, James E., Ingleson, Michael J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577509/ https://www.ncbi.nlm.nih.gov/pubmed/28608991 http://dx.doi.org/10.1002/anie.201705100

Ejemplares similares

N‐Methyl‐Benzothiazolium Salts as Carbon Lewis Acids for Si−H σ‐Bond Activation and Catalytic (De)hydrosilylation
por: Fasano, Valerio, et al.
Publicado: (2016)

Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids
por: Lawrence, Elliot J., et al.
Publicado: (2016)

Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations
por: Fasano, Valerio, et al.
Publicado: (2017)

Contrasting Frustrated Lewis Pair Reactivity with Selenium‐ and Boron‐Based Lewis Acids
por: Wilkins, Lewis C., et al.
Publicado: (2016)

Formation of C(sp(2))—Boronate Esters by Borylative Cyclization of Alkynes Using BCl(3)
por: Warner, Andrew J., et al.
Publicado: (2015)

A Phosphanyl‐Phosphagallene that Functions as a Frustrated Lewis Pair
por: Wilson, Daniel W. N., et al.
Publicado: (2020)

Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
por: Hidalgo, Nereida, et al.
Publicado: (2020)

N-Heterocycle-Ligated Borocations as Highly Tunable Carbon Lewis Acids
por: Radcliffe, James E., et al.
Publicado: (2017)

An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair
por: Holtkamp, Philipp, et al.
Publicado: (2020)

Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation
por: Grundy, Matthew E., et al.
Publicado: (2023)

Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis
por: Köring, Laura, et al.
Publicado: (2021)

Mapping Active Site Geometry to Activity in Immobilized Frustrated Lewis Pair Catalysts
por: Das, Shubhajit, et al.
Publicado: (2022)

Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO(2) in the Presence of Silylhalides
por: Wang, Tongtong, et al.
Publicado: (2021)

Semihydrogenation of Alkynes Catalyzed by a Pyridone Borane Complex: Frustrated Lewis Pair Reactivity and Boron–Ligand Cooperation in Concert
por: Wech, Felix, et al.
Publicado: (2020)

Solid state frustrated Lewis pair chemistry
por: Wang, Long, et al.
Publicado: (2018)

Reactions of Diethylazo‐Dicarboxylate with Frustrated Lewis Pairs
por: Mandal, Dipendu, et al.
Publicado: (2022)

Reactions of Frustrated Lewis Pairs with Chloro‐Diazirines: Cleavage of N=N Double Bonds
por: Mandal, Dipendu, et al.
Publicado: (2022)

Selective Boryl‐Anion Migration in a Vinyl sp(2)−sp(3) Diborane Induced by Soft Borane Lewis Acids
por: Fasano, Valerio, et al.
Publicado: (2018)

New Insights in Frustrated Lewis Pair Chemistry with Azides
por: Boom, Devin H. A., et al.
Publicado: (2019)

Single‐Electron Transfer in Frustrated Lewis Pair Chemistry
por: Holtrop, Flip, et al.
Publicado: (2020)

Frustrated Lewis Pairs in Heterogeneous Catalysis: Theoretical Insights
por: Wan, Qiang, et al.
Publicado: (2022)

syn-1,2-Carboboration of Alkynes with Borenium Cations
por: Cade, Ian A, et al.
Publicado: (2014)

Cyclic Ether Triggers for Polymeric Frustrated Lewis Pair Gels
por: Yolsal, Utku, et al.
Publicado: (2021)

A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes
por: Hoshimoto, Yoichi, et al.
Publicado: (2015)

Boranyl‐Functionalized [Ge(9)] Clusters: Providing the Idea of Intramolecular Ge/B Frustrated Lewis Pairs
por: Wallach, Christoph, et al.
Publicado: (2020)

Hydrogen Activation by Frustrated and Not So Frustrated Lewis Pairs Based on Pyramidal Lewis Acid 9-Boratriptycene: A Computational Study
por: Pomogaeva, Anna V., et al.
Publicado: (2022)

Exploiting the Electronic Tuneability of Carboranes as Supports for Frustrated Lewis Pairs
por: Benton, Amanda, et al.
Publicado: (2018)

Parallels between Metal‐Ligand Cooperativity and Frustrated Lewis Pairs
por: Habraken, Evi R. M., et al.
Publicado: (2019)

Theoretical Characterization of New Frustrated Lewis Pairs for Responsive Materials
por: Galdeano, Maialen, et al.
Publicado: (2021)

Metal-Free Dihydrogen Oxidation by a Borenium Cation: A Combined Electrochemical/Frustrated Lewis Pair Approach**
por: Lawrence, Elliot J, et al.
Publicado: (2014)

Colorimetric Metal‐Free Detection of Carbon Monoxide: Reversible CO Uptake by a BNB Frustrated Lewis Pair
por: Zheng, Xiongfei, et al.
Publicado: (2021)

Bifunctional Fluorophosphonium Triflates as Intramolecular Frustrated Lewis Pairs: Reversible CO(2) Sequestration and Binding of Carbonyls, Nitriles and Acetylenes
por: Guo, Chun‐Xiang, et al.
Publicado: (2021)

Trioxatriangulenium (TOTA(+)) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry
por: Shaikh, Aslam C., et al.
Publicado: (2021)

Facile Protocol for Water-Tolerant “Frustrated Lewis Pair”-Catalyzed Hydrogenation
por: Scott, Daniel J., et al.
Publicado: (2015)

CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template
por: Wang, Tongdao, et al.
Publicado: (2017)

Carbon dioxide reduction by an Al–O–P frustrated Lewis pair
por: Wickemeyer, Lucas, et al.
Publicado: (2022)

Polymeric frustrated Lewis pairs in CO(2)/cyclic ether coupling catalysis
por: Horton, Thomas A. R., et al.
Publicado: (2022)

A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis‐Pair and Reductive Elimination
por: Holtkamp, Philipp, et al.
Publicado: (2020)

Metal–ligand multiple bonds as frustrated Lewis pairs for C–H functionalization
por: Whited, Matthew T
Publicado: (2012)

Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
por: Sáez, Rubén, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_rkg4vvpai7ee41jpbvqim1p45j