Alkynyl Moiety for Triggering 1,2‐Metallate Shifts: Enantiospecific sp(2)–sp(3) Coupling of Boronic Esters with p‐Arylacetylenes

The enantiospecific coupling of secondary and tertiary boronic esters to aromatics has been investigated. Using p‐lithiated phenylacetylenes and a range of boronic esters coupling has been achieved by the addition of N‐bromosuccinimide (NBS). The alkyne functionality of the intermediate boronate com...

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Detalles Bibliográficos
Autores principales: Ganesh, Venkataraman, Odachowski, Marcin, Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577510/
https://www.ncbi.nlm.nih.gov/pubmed/28618129
http://dx.doi.org/10.1002/anie.201703894

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577510/
https://www.ncbi.nlm.nih.gov/pubmed/28618129
http://dx.doi.org/10.1002/anie.201703894

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