Divergent reactivities in fluoronation of allylic alcohols: synthesis of Z-fluoroalkenes via carbon–carbon bond cleavage

An unconventional cleavage of an unstrained carbon–carbon bond in allylic alcohols can be induced by the use of N-fluorobenzenesulfonimide (NFSI) under catalyst-free conditions. By using this simple procedure, a wide range of functionalized Z-fluoroalkenes can be accessed in high yield and selectivi...

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Detalles Bibliográficos
Autores principales: Liu, Tang-Lin, Wu, Ji’En, Zhao, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578365/
https://www.ncbi.nlm.nih.gov/pubmed/28966780
http://dx.doi.org/10.1039/c7sc00483d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578365/
https://www.ncbi.nlm.nih.gov/pubmed/28966780
http://dx.doi.org/10.1039/c7sc00483d

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