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Protein modification via alkyne hydrosilylation using a substoichiometric amount of ruthenium(ii) catalyst
Transition metal catalysis has emerged as a powerful strategy to expand synthetic flexibility of protein modification. Herein, we report a cationic Ru(ii) system that enables the first example of alkyne hydrosilylation between dimethylarylsilanes and O-propargyl-functionalized proteins using a subst...
Autores principales: | , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578368/ https://www.ncbi.nlm.nih.gov/pubmed/28966779 http://dx.doi.org/10.1039/c6sc05313k |