Protein modification via alkyne hydrosilylation using a substoichiometric amount of ruthenium(ii) catalyst

Transition metal catalysis has emerged as a powerful strategy to expand synthetic flexibility of protein modification. Herein, we report a cationic Ru(ii) system that enables the first example of alkyne hydrosilylation between dimethylarylsilanes and O-propargyl-functionalized proteins using a subst...

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Detalles Bibliográficos
Autores principales: Kwan, Terence T.-L., Boutureira, Omar, Frye, Elizabeth C., Walsh, Stephen J., Gupta, Moni K., Wallace, Stephen, Wu, Yuteng, Zhang, Fengzhi, Sore, Hannah F., Galloway, Warren R. J. D., Chin, Jason W., Welch, Martin, Bernardes, Gonçalo J. L., Spring, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578368/
https://www.ncbi.nlm.nih.gov/pubmed/28966779
http://dx.doi.org/10.1039/c6sc05313k

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