Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes

The one-electron reduction of a cationic (allenylidene)[cyclic(alkyl) (amino)carbene]gold(i) complex leads to the corresponding neutral, paramagnetic, formally gold(0) complex. DFT calculations reveal that the spin density of this highly robust coinage metal complex is mainly located on the allenyli...

Descripción completa

Detalles Bibliográficos
Autores principales: Jin, Liqun, Melaimi, Mohand, Kostenko, Arseni, Karni, Miriam, Apeloig, Yitzhak, Moore, Curtis E., Rheingold, Arnold L., Bertrand, Guy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5580305/
https://www.ncbi.nlm.nih.gov/pubmed/28966767
http://dx.doi.org/10.1039/c5sc03654b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5580305/
https://www.ncbi.nlm.nih.gov/pubmed/28966767
http://dx.doi.org/10.1039/c5sc03654b

Ejemplares similares