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Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes

The one-electron reduction of a cationic (allenylidene)[cyclic(alkyl) (amino)carbene]gold(i) complex leads to the corresponding neutral, paramagnetic, formally gold(0) complex. DFT calculations reveal that the spin density of this highly robust coinage metal complex is mainly located on the allenyli...

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Detalles Bibliográficos
Autores principales:	Jin, Liqun, Melaimi, Mohand, Kostenko, Arseni, Karni, Miriam, Apeloig, Yitzhak, Moore, Curtis E., Rheingold, Arnold L., Bertrand, Guy
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5580305/ https://www.ncbi.nlm.nih.gov/pubmed/28966767 http://dx.doi.org/10.1039/c5sc03654b

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