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Anti-cooperative supramolecular polymerization: a new K (2)–K model applied to the self-assembly of perylene bisimide dye proceeding via well-defined hydrogen-bonded dimers

A perylene bisimide dye bearing amide functionalities at the imide positions derived from amino acid l-alanine and a dialkoxy-substituted benzyl amine self-assembles into tightly bound dimers by π–π-stacking and hydrogen bonding in chloroform. In less polar or unpolar solvents like toluene and methy...

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Detalles Bibliográficos
Autores principales: Gershberg, Jana, Fennel, Franziska, Rehm, Thomas H., Lochbrunner, Stefan, Würthner, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5582317/
https://www.ncbi.nlm.nih.gov/pubmed/28966774
http://dx.doi.org/10.1039/c5sc03759j