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Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups

Three compounds with phenyl (1), 4-tert-butylphenyl (2) and 4-N,N-diphenylaminophenyl (3) groups attached to bis(fluoromesityl)boryl ((FMes)(2)B) through B–C bonds have been prepared. The restricted rotation about the B–C bonds of boron-bonded aryl rings in solution has been studied by variable-temp...

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Detalles Bibliográficos
Autores principales: Zhang, Zuolun, Edkins, Robert M., Nitsch, Jörn, Fucke, Katharina, Steffen, Andreas, Longobardi, Lauren E., Stephan, Douglas W., Lambert, Christoph, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5586071/
https://www.ncbi.nlm.nih.gov/pubmed/28966759
http://dx.doi.org/10.1039/c4sc02410a