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Ultrafast isomerization in acetylene dication after carbon K-shell ionization

Ultrafast proton migration and isomerization are key processes for acetylene and its ions. However, the mechanism for ultrafast isomerization of acetylene [HCCH](2+) to vinylidene [H(2)CC](2+) dication remains nebulous. Theoretical studies show a large potential barrier ( > 2 eV) for isomerizatio...

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Detalles Bibliográficos
Autores principales: Li, Zheng, Inhester, Ludger, Liekhus-Schmaltz, Chelsea, Curchod, Basile F. E., Snyder, James W., Medvedev, Nikita, Cryan, James, Osipov, Timur, Pabst, Stefan, Vendrell, Oriol, Bucksbaum, Phil, Martinez, Todd J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5587545/
https://www.ncbi.nlm.nih.gov/pubmed/28878226
http://dx.doi.org/10.1038/s41467-017-00426-6