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Diaryldichalcogenide radical cations

One-electron oxidation of two series of diaryldichalcogenides (C(6)F(5)E)(2) (13a–c) and (2,6-Mes(2)C(6)H(3)E)(2) (16a–c) was studied (E = S, Se, Te). The reaction of 13a and 13b with AsF(5) and SbF(5) gave rise to the formation of thermally unstable radical cations [(C(6)F(5)S)(2)]˙(+) (14a) and [(...

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Detalles Bibliográficos
Autores principales: Mallow, Ole, Khanfar, Monther A., Malischewski, Moritz, Finke, Pamela, Hesse, Malte, Lork, Enno, Augenstein, Timo, Breher, Frank, Harmer, Jeffrey R., Vasilieva, Nadezhda V., Zibarev, Andrey, Bogomyakov, Artem S., Seppelt, Konrad, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588450/
https://www.ncbi.nlm.nih.gov/pubmed/28936305
http://dx.doi.org/10.1039/c4sc02964j