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Pseudosymmetry and high Z′ structures: the case of rac-(2R,2′R,5′S)-2-methyl-5′-[(1R,2R,5S,5′S)-1,4,4,5′-tetramethyldihydro-3′H-3,8-dioxaspiro[bicyclo[3.2.1]octane-2,2′-furan]-5′-yl]-3,4,1′,2′,3′,4′-hexahydro-[2,2′-bifuran]-5(2H)-one
The title compound, C(22)H(34)O(6), is one of the products obtained by oxidation of squalene with the catalytic system RuO(4)(cat.)/NaIO(4). It crystallizes in the P-1 space group, with four crystallographically independent molecules related by a pseudo-C (2) symmetry axis. The structural analysis...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588561/ https://www.ncbi.nlm.nih.gov/pubmed/28932455 http://dx.doi.org/10.1107/S2056989017010805 |