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Phosphine-catalyzed enantioselective [3 + 2] cycloadditions of γ-substituted allenoates with β-perfluoroalkyl enones

The enantioselective construction of densely functionalized cyclopentene bearing contiguous three stereocenters has been a challenging task in organic synthesis. Herein, we present a phoshine-catalyzed highly regio-, diastereo- and enantioselective [3 + 2] cycloaddition of γ-substituted allenoates w...

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Detalles Bibliográficos
Autores principales: Zhou, Wei, Wang, Huamin, Tao, Mengna, Zhu, Chao-Ze, Lin, Tao-Yan, Zhang, Junliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5590097/
https://www.ncbi.nlm.nih.gov/pubmed/28936335
http://dx.doi.org/10.1039/c7sc01432e