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Double C–H bond activation of acetylene by atomic boron in forming aromatic cyclic-HBC(2)BH in solid neon
The organo-boron species formed from the reactions of boron atoms with acetylene in solid neon are investigated using matrix isolation infrared spectroscopy with isotopic substitutions as well as quantum chemical calculations. Besides the previously reported single C–H bond activation species, a cyc...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5590098/ https://www.ncbi.nlm.nih.gov/pubmed/28936331 http://dx.doi.org/10.1039/c7sc01399j |