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Small endohedral metallofullerenes: exploration of the structure and growth mechanism in the Ti@C(2n) (2n = 26–50) family

The formation of the smallest fullerene, C(28), was recently reported using gas phase experiments combined with high-resolution FT-ICR mass spectrometry. An internally located group IV metal stabilizes the highly strained non-IPR C(28) cage by charge transfer (IPR = isolated pentagon rule). Ti@C(44)...

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Detalles Bibliográficos
Autores principales: Mulet-Gas, Marc, Abella, Laura, Dunk, Paul W., Rodríguez-Fortea, Antonio, Kroto, Harold W., Poblet, Josep M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5590485/
https://www.ncbi.nlm.nih.gov/pubmed/28936315
http://dx.doi.org/10.1039/c4sc02268h