Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines

We have devised a highly regio- and enantioselective iridium-catalyzed allylic amination reaction with the sulfur-stabilized aza-ylide, S,S-diphenylsulfilimine. This process provides a robust and scalable method for the construction of aryl-, alkyl- and alkenyl-substituted C-chiral allylic sulfilimi...

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Detalles Bibliográficos
Autores principales: Grange, Rebecca L., Clizbe, Elizabeth A., Counsell, Emma J., Evans, P. Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5592745/
https://www.ncbi.nlm.nih.gov/pubmed/28936319
http://dx.doi.org/10.1039/c4sc01317d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5592745/
https://www.ncbi.nlm.nih.gov/pubmed/28936319
http://dx.doi.org/10.1039/c4sc01317d

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