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Transition-metal-free controlled polymerization for poly(p-aryleneethynylene)s

A transition-metal-free controlled polymerization for the attainment of poly(p-aryleneethynylene)s is developed. The polymerization of 1-pentafluorophenyl-4-[(trimethylsilyl)ethynyl]benzene with a catalytic amount of fluoride anions proceeds in a chain-growth-like manner to afford polymers with cont...

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Detalles Bibliográficos
Autores principales: Sanji, Takanobu, Motoshige, Asahi, Komiyama, Hideaki, Kakinuma, Junko, Ushikubo, Rie, Watanabe, Satoru, Iyoda, Tomokazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5592747/
https://www.ncbi.nlm.nih.gov/pubmed/28936304
http://dx.doi.org/10.1039/c4sc02872d