Aminofluorination: transition-metal-free N–F bond insertion into diazocarbonyl compounds

Gem-aminofluorination of diazocarbonyl compounds has been achieved for the first time. This reaction proceeds under mild conditions and does not require any transition-metal promoter or catalyst. Treatment of diazoesters with N-fluorobenzenesulfonimide (NFSI), which serves as both a fluorine and nit...

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Detalles Bibliográficos
Autores principales: Chen, Gui, Song, Jinshuai, Yu, Yinghua, Luo, Xuesong, Li, Chunsen, Huang, Xueliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5595123/
https://www.ncbi.nlm.nih.gov/pubmed/28959390
http://dx.doi.org/10.1039/c5sc04237b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5595123/
https://www.ncbi.nlm.nih.gov/pubmed/28959390
http://dx.doi.org/10.1039/c5sc04237b

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