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Synthesis and crystal structures of [Ph(3)PCH(2)PPh(3)]I(2) dichloromethane disolvate and [Ph(3)PCH(2)PPh(3)](BI(4))(2)
Reaction of BI(3) with carbodiphosphorane, C(PPh(3))(2), gives a mixture of the dicationic compounds, methylenebis(triphenylphosphonium) diiodide dichloromethane disolvate, C(37)H(32)P(2) (2+)·2I(−)·2CH(2)Cl(2) or [Ph(3)PCH(2)PPh(3)]I(2)·2CH(2)Cl(2) (I), methylenebis(triphenylphosphonium...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598861/ https://www.ncbi.nlm.nih.gov/pubmed/28932449 http://dx.doi.org/10.1107/S2056989017010295 |