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Synthesis of Highly Oxygenated Carbocycles by Stereoselective Coupling of Alkynes to 1,3- and 1,4-Dicarbonyl Systems

[Image: see text] Densely substituted and highly oxygenated carbocycles are challenging targets for synthesis. In particular, those possessing numerous contiguous, fully substituted carbon atoms (i.e., tertiary alcohols and quaternary centers) are often not accessible in a direct fashion, necessitat...

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Detalles Bibliográficos
Autores principales: Kier, Matthew J., Leon, Robert M., O’Rourke, Natasha F., Rheingold, Arnold L., Micalizio, Glenn C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5600187/
https://www.ncbi.nlm.nih.gov/pubmed/28844136
http://dx.doi.org/10.1021/jacs.7b06286