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Unexpected Interactions between Alkyl Straps and Pyridine Ligands in Sulfur-Strapped Porphyrin Nanorings

[Image: see text] Strapped or “basket-handle” porphyrins have been investigated previously as hemoglobin mimics and catalysts. The facial selectivity of their interactions with axial ligands is a sensitive test for noncovalent bonding. Here the binding of pyridyl ligands to zinc porphyrins with thio...

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Detalles Bibliográficos
Autores principales: Roche, Cécile, Luo, Qianfu, Gil-Ramírez, Guzmán, Jiang, Hua-Wei, Kohn, Daniel R., Xiong, Yaoyao, Thompson, Amber L., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5600440/
https://www.ncbi.nlm.nih.gov/pubmed/28654266
http://dx.doi.org/10.1021/acs.joc.7b01128