Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α‐Oxy‐ and α‐Thio‐Substituted Organolithium Species

Nonstabilized α‐O‐substituted tertiary organolithium species are difficult to generate, and the α‐S‐substituted analogues are configurationally unstable. We now report that they can both be generated easily and trapped with a range of electrophiles with high enantioselectivity, providing ready acces...

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Detalles Bibliográficos
Autores principales: Pulis, Alexander P., Varela, Ana, Citti, Cinzia, Songara, Pradip, Leonori, Daniele, Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5601220/
https://www.ncbi.nlm.nih.gov/pubmed/28783238
http://dx.doi.org/10.1002/anie.201706722

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5601220/
https://www.ncbi.nlm.nih.gov/pubmed/28783238
http://dx.doi.org/10.1002/anie.201706722

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