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Cesium's Off‐the‐Map Valence Orbital
The T(d)‐symmetric [CsO(4)](+) ion, featuring Cs in an oxidation state of 9, is computed to be a minimum. Cs uses outer core 5s and 5p orbitals to bind the oxygen atoms. The valence Cs 6s orbital lies too high to be involved in bonding, and contributes to Rydberg levels only. From a molecular orbita...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5601296/ https://www.ncbi.nlm.nih.gov/pubmed/28643352 http://dx.doi.org/10.1002/anie.201704118 |