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A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights
A well-defined NHC–Ir(iii) catalyst, [Ir(H)(2)(IPr)(py)(3)][BF(4)] (IPr = 1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene), that provides access to a wide range of aryl- and heteroaryl-silanes by intermolecular dehydrogenative C–H bond silylation has been prepared and fully characterized. The dire...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5602144/ https://www.ncbi.nlm.nih.gov/pubmed/28959403 http://dx.doi.org/10.1039/c6sc04899d |