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A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights

A well-defined NHC–Ir(iii) catalyst, [Ir(H)(2)(IPr)(py)(3)][BF(4)] (IPr = 1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene), that provides access to a wide range of aryl- and heteroaryl-silanes by intermolecular dehydrogenative C–H bond silylation has been prepared and fully characterized. The dire...

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Detalles Bibliográficos
Autores principales:	Rubio-Pérez, Laura, Iglesias, Manuel, Munárriz, Julen, Polo, Victor, Passarelli, Vincenzo, Pérez-Torrente, Jesús J., Oro, Luis A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5602144/ https://www.ncbi.nlm.nih.gov/pubmed/28959403 http://dx.doi.org/10.1039/c6sc04899d

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