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Single operation palladium catalysed C(sp(3))–H functionalisation of tertiary aldehydes: investigations into transient imine directing groups
Simple amine and diamine derivatives can promote the palladium catalysed direct β-C–H arylation of aliphatic aldehydes via transient imine formation. Trifluoroacetate was shown to be crucial in promoting the reaction. Sub-stoichiometric quantities of simple N-tosylethylenediamine was shown to form a...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5603794/ https://www.ncbi.nlm.nih.gov/pubmed/28959406 http://dx.doi.org/10.1039/c7sc01218g |