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Single operation palladium catalysed C(sp(3))–H functionalisation of tertiary aldehydes: investigations into transient imine directing groups

Simple amine and diamine derivatives can promote the palladium catalysed direct β-C–H arylation of aliphatic aldehydes via transient imine formation. Trifluoroacetate was shown to be crucial in promoting the reaction. Sub-stoichiometric quantities of simple N-tosylethylenediamine was shown to form a...

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Detalles Bibliográficos
Autores principales:	St John-Campbell, S., White, A. J. P., Bull, J. A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5603794/ https://www.ncbi.nlm.nih.gov/pubmed/28959406 http://dx.doi.org/10.1039/c7sc01218g

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