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Metal exchange in lithiocuprates: implications for our understanding of structure and reactivity
New reagents have been sought for directed ortho cupration in which the use of cyanide reagents is eliminated. CuOCN reacts with excess TMPLi (TMP = 2,2,6,6-tetramethylpiperidide) in the presence of limited donor solvent to give crystals that are best represented as (TMP)(2)Cu(0.1)Li(0.9)(OCN)Li(2)(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5603898/ https://www.ncbi.nlm.nih.gov/pubmed/28959414 http://dx.doi.org/10.1039/c7sc01423f |