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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

The halogenation of metallapentalyne led to the formation of metallapentalenes, which were fully characterized and studied by DFT calculations. The experimental and computational studies indicate that four resonance forms contribute to the overall structure of the metallapentalenes, and one resonanc...

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Detalles Bibliográficos
Autores principales: Luo, Ming, Zhu, Congqing, Chen, Lina, Zhang, Hong, Xia, Haiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5604402/
https://www.ncbi.nlm.nih.gov/pubmed/28959393
http://dx.doi.org/10.1039/c5sc03963k