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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion
The halogenation of metallapentalyne led to the formation of metallapentalenes, which were fully characterized and studied by DFT calculations. The experimental and computational studies indicate that four resonance forms contribute to the overall structure of the metallapentalenes, and one resonanc...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5604402/ https://www.ncbi.nlm.nih.gov/pubmed/28959393 http://dx.doi.org/10.1039/c5sc03963k |