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Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes
For the first time, α-formyldiazoacetates have been successfully applied for the asymmetric cyclopropanation of alkenes via Co(ii)-based metalloradical catalysis. The cobalt(ii) complex of the D (2)-symmetric chiral amidoporphyrin [Co(3,5-Di( t )Bu-ChenPhyrin)] is an effective metalloradical catalys...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5605771/ https://www.ncbi.nlm.nih.gov/pubmed/28959396 http://dx.doi.org/10.1039/c7sc00658f |