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Ti(Oi-Pr)(4)-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications

Stereoselective construction of polycyclic rings with all-carbon quaternary centers, and vicinal all-carbon quaternary stereocenters, remains a significant challenge in organic synthesis. These structures can be found in a wide range of polycyclic natural products and drug molecules. Here we report...

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Detalles Bibliográficos
Autores principales: Yang, Baochao, Lin, Kuaikuai, Shi, Yingbo, Gao, Shuanhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607006/
https://www.ncbi.nlm.nih.gov/pubmed/28931807
http://dx.doi.org/10.1038/s41467-017-00440-8