Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Herein, we report the synthesis and characterisation of the first terminal uranium(v) sulfide and a related U(V) trithiocarbonate complex supported by sterically demanding tris(tert-butoxy)siloxide ligands. The reaction of the potassium-bound U(V) imido complex, [U(NAd){OSi(OtBu)(3)}(4)K] (4), with...

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Detalles Bibliográficos
Autores principales: Kelly, Rory P., Falcone, Marta, Lamsfus, Carlos Alvarez, Scopelliti, Rosario, Maron, Laurent, Meyer, Karsten, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607896/
https://www.ncbi.nlm.nih.gov/pubmed/28970911
http://dx.doi.org/10.1039/c7sc01111c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607896/
https://www.ncbi.nlm.nih.gov/pubmed/28970911
http://dx.doi.org/10.1039/c7sc01111c

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