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Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide
Herein, we report the synthesis and characterisation of the first terminal uranium(v) sulfide and a related U(V) trithiocarbonate complex supported by sterically demanding tris(tert-butoxy)siloxide ligands. The reaction of the potassium-bound U(V) imido complex, [U(NAd){OSi(OtBu)(3)}(4)K] (4), with...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607896/ https://www.ncbi.nlm.nih.gov/pubmed/28970911 http://dx.doi.org/10.1039/c7sc01111c |