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The Role of Rydberg–Valence Coupling in the Ultrafast Relaxation Dynamics of Acetone

[Image: see text] The electronic structure of excited states of acetone is represented by a Rydberg manifold that is coupled to valence states which provide very fast and efficient relaxation pathways. We observe and characterize the transfer of population from photoexcited Rydberg states (6p, 6d, 7...

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Detalles Bibliográficos
Autores principales: Koch, Markus, Thaler, Bernhard, Heim, Pascal, Ernst, Wolfgang E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5608382/
https://www.ncbi.nlm.nih.gov/pubmed/28737942
http://dx.doi.org/10.1021/acs.jpca.7b05012