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A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface

Oxidation of bromide in aqueous environments initiates the formation of molecular halogen compounds, which is important for the global tropospheric ozone budget. In the aqueous bulk, oxidation of bromide by ozone involves a [Br•OOO(−)] complex as intermediate. Here we report liquid jet X-ray photoel...

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Detalles Bibliográficos
Autores principales: Artiglia, Luca, Edebeli, Jacinta, Orlando, Fabrizio, Chen, Shuzhen, Lee, Ming-Tao, Corral Arroyo, Pablo, Gilgen, Anina, Bartels-Rausch, Thorsten, Kleibert, Armin, Vazdar, Mario, Andres Carignano, Marcelo, Francisco, Joseph S., Shepson, Paul B., Gladich, Ivan, Ammann, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5615067/
https://www.ncbi.nlm.nih.gov/pubmed/28951540
http://dx.doi.org/10.1038/s41467-017-00823-x