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Metal-free direct alkylation of unfunctionalized allylic/benzylic sp(3) C–H bonds via photoredox induced radical cation deprotonation

Despite notable recent efforts, a catalytic and convenient strategy for the direct alkylation of unactivated allylic or benzylic sp(3) C–H bonds remains a formidable challenge facing the synthesis community. We herein report an unprecedented allylic/benzylic alkylation using only an organo-photoredo...

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Detalles Bibliográficos
Autores principales: Zhou, Rong, Liu, Haiwang, Tao, Hairong, Yu, Xingjian, Wu, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618257/
https://www.ncbi.nlm.nih.gov/pubmed/28970885
http://dx.doi.org/10.1039/c7sc00953d