Chiral phosphine-mediated intramolecular [3 + 2] annulation: enhanced enantioselectivity by achiral Brønsted acid

Enantioselective intramolecular [3 + 2] annulation of chalcones bearing an allene moiety has been successfully developed. The reaction was effectively promoted by amino acid-derived phosphines, in combination with achiral Brønsted acids. Dihydrocoumarin architectures were constructed in high yields...

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Detalles Bibliográficos
Autores principales: Yao, Weijun, Yu, Zhaoyuan, Wen, Shan, Ni, Huanzhen, Ullah, Nisar, Lan, Yu, Lu, Yixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618691/
https://www.ncbi.nlm.nih.gov/pubmed/28970906
http://dx.doi.org/10.1039/c7sc00952f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618691/
https://www.ncbi.nlm.nih.gov/pubmed/28970906
http://dx.doi.org/10.1039/c7sc00952f

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