Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions

The first general and efficient non-noble metal-catalysed reductive C2-alkoxylation of cyclic imides (phthalimides and succinimides) is presented. Crucial for the success is the use of [Co(BF(4))(2)·6H(2)O/triphos (L1)] combination and no external additives are required. Using the optimal cobalt-sys...

Descripción completa

Detalles Bibliográficos
Autores principales: Cabrero-Antonino, Jose R., Adam, Rosa, Papa, Veronica, Holsten, Mattes, Junge, Kathrin, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618770/
https://www.ncbi.nlm.nih.gov/pubmed/28970933
http://dx.doi.org/10.1039/c7sc01175j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618770/
https://www.ncbi.nlm.nih.gov/pubmed/28970933
http://dx.doi.org/10.1039/c7sc01175j

Ejemplares similares