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Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions
The first general and efficient non-noble metal-catalysed reductive C2-alkoxylation of cyclic imides (phthalimides and succinimides) is presented. Crucial for the success is the use of [Co(BF(4))(2)·6H(2)O/triphos (L1)] combination and no external additives are required. Using the optimal cobalt-sys...
Autores principales: | Cabrero-Antonino, Jose R., Adam, Rosa, Papa, Veronica, Holsten, Mattes, Junge, Kathrin, Beller, Matthias |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618770/ https://www.ncbi.nlm.nih.gov/pubmed/28970933 http://dx.doi.org/10.1039/c7sc01175j |
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