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Reversible C–C bond formation at a triply cyclometallated platinum(iv) centre

The oxidation of the tribenzylphosphine derivative of the doubly cylcometallated platinum(ii) complex of diphenylpyridine, 1, with PhICl(2) led, as a first step, to the formation of a highly electrophilic metal centre which attacked the benzyl phosphine to give a triply cyclometallated species as th...

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Detalles Bibliográficos
Autores principales: Shaw, Paul A., Clarkson, Guy J., Rourke, Jonathan P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618794/
https://www.ncbi.nlm.nih.gov/pubmed/28970934
http://dx.doi.org/10.1039/c7sc01361b