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Reversible C–C bond formation at a triply cyclometallated platinum(iv) centre
The oxidation of the tribenzylphosphine derivative of the doubly cylcometallated platinum(ii) complex of diphenylpyridine, 1, with PhICl(2) led, as a first step, to the formation of a highly electrophilic metal centre which attacked the benzyl phosphine to give a triply cyclometallated species as th...
Autores principales: | Shaw, Paul A., Clarkson, Guy J., Rourke, Jonathan P. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5618794/ https://www.ncbi.nlm.nih.gov/pubmed/28970934 http://dx.doi.org/10.1039/c7sc01361b |
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