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The Role of Surface-Bound Dihydropyridine Analogues in Pyridine-Catalyzed CO(2) Reduction over Semiconductor Photoelectrodes

[Image: see text] We propose a general reaction mechanism for the pyridine (Py)-catalyzed reduction of CO(2) over GaP(111), CdTe(111), and CuInS(2)(112) photoelectrode surfaces. This mechanism proceeds via formation of a surface-bound dihydropyridine (DHP) analogue, which is a newly postulated inter...

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Detalles Bibliográficos
Autores principales: Senftle, Thomas P., Lessio, Martina, Carter, Emily A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5620980/
https://www.ncbi.nlm.nih.gov/pubmed/28979938
http://dx.doi.org/10.1021/acscentsci.7b00233