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The Role of Surface-Bound Dihydropyridine Analogues in Pyridine-Catalyzed CO(2) Reduction over Semiconductor Photoelectrodes
[Image: see text] We propose a general reaction mechanism for the pyridine (Py)-catalyzed reduction of CO(2) over GaP(111), CdTe(111), and CuInS(2)(112) photoelectrode surfaces. This mechanism proceeds via formation of a surface-bound dihydropyridine (DHP) analogue, which is a newly postulated inter...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5620980/ https://www.ncbi.nlm.nih.gov/pubmed/28979938 http://dx.doi.org/10.1021/acscentsci.7b00233 |