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Nitro-enabled catalytic enantioselective formal umpolung alkenylation of β-ketoesters
A formal umpolung strategy is presented for the enantioselective installation of an alkenyl group with a terminal double bond at a tertiary center. This one-pot two-step sequence relies on the unique features of the nitro group, which after inverting the polarity of the alkenylating agent toward the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625255/ https://www.ncbi.nlm.nih.gov/pubmed/28989696 http://dx.doi.org/10.1039/c7sc02232h |