Evaluating the electronic structure of formal Ln(II) ions in Ln(II)(C(5)H(4)SiMe(3))(3) (1–) using XANES spectroscopy and DFT calculations

The isolation of [K(2.2.2-cryptand)][Ln(C(5)H(4)SiMe(3))(3)], formally containing Ln(II), for all lanthanides (excluding Pm) was surprising given that +2 oxidation states are typically regarded as inaccessible for most 4f-elements. Herein, X-ray absorption near-edge spectroscopy (XANES), ground-stat...

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Detalles Bibliográficos
Autores principales: Fieser, Megan E., Ferrier, Maryline G., Su, Jing, Batista, Enrique, Cary, Samantha K., Engle, Jonathan W., Evans, William J., Lezama Pacheco, Juan S., Kozimor, Stosh A., Olson, Angela C., Ryan, Austin J., Stein, Benjamin W., Wagner, Gregory L., Woen, David H., Vitova, Tonya, Yang, Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625586/
https://www.ncbi.nlm.nih.gov/pubmed/28989638
http://dx.doi.org/10.1039/c7sc00825b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625586/
https://www.ncbi.nlm.nih.gov/pubmed/28989638
http://dx.doi.org/10.1039/c7sc00825b

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