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On the incompatibility of lithium–O(2) battery technology with CO(2)

When solubilized in a hexacarboxamide cryptand anion receptor, the peroxide dianion reacts rapidly with CO(2) in polar aprotic organic media to produce hydroperoxycarbonate (HOOCO(2) (–)) and peroxydicarbonate ((–)O(2)COOCO(2) (–)). Peroxydicarbonate is subject to thermal fragmentation into two equi...

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Detalles Bibliográficos
Autores principales: Zhang, Shiyu, Nava, Matthew J., Chow, Gary K., Lopez, Nazario, Wu, Gang, Britt, David R., Nocera, Daniel G., Cummins, Christopher C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625616/
https://www.ncbi.nlm.nih.gov/pubmed/28989641
http://dx.doi.org/10.1039/c7sc01230f