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On the incompatibility of lithium–O(2) battery technology with CO(2)
When solubilized in a hexacarboxamide cryptand anion receptor, the peroxide dianion reacts rapidly with CO(2) in polar aprotic organic media to produce hydroperoxycarbonate (HOOCO(2) (–)) and peroxydicarbonate ((–)O(2)COOCO(2) (–)). Peroxydicarbonate is subject to thermal fragmentation into two equi...
Autores principales: | Zhang, Shiyu, Nava, Matthew J., Chow, Gary K., Lopez, Nazario, Wu, Gang, Britt, David R., Nocera, Daniel G., Cummins, Christopher C. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625616/ https://www.ncbi.nlm.nih.gov/pubmed/28989641 http://dx.doi.org/10.1039/c7sc01230f |
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