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Photoredox mediated nickel catalyzed C(sp(3))–H thiocarbonylation of ethers

The first direct C(sp(3))–H thiocarbonylation reaction is achieved by visible light photoredox/Ni dual catalysis. The thioester group of thiobenzoate is transferred to the α-oxy carbon of various cyclic/acyclic ethers, which is the opposite to the commonly expected chemical reactivity involving acyl...

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Detalles Bibliográficos
Autores principales: Kang, Byungjoon, Hong, Soon Hyeok
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627187/
https://www.ncbi.nlm.nih.gov/pubmed/28989688
http://dx.doi.org/10.1039/c7sc02516e