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Photoredox mediated nickel catalyzed C(sp(3))–H thiocarbonylation of ethers
The first direct C(sp(3))–H thiocarbonylation reaction is achieved by visible light photoredox/Ni dual catalysis. The thioester group of thiobenzoate is transferred to the α-oxy carbon of various cyclic/acyclic ethers, which is the opposite to the commonly expected chemical reactivity involving acyl...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627187/ https://www.ncbi.nlm.nih.gov/pubmed/28989688 http://dx.doi.org/10.1039/c7sc02516e |