Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U(IV)–E–U(IV) cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange

We report the synthesis and characterisation of a family of diuranium(iv)-μ-chalcogenide complexes including a detailed examination of their electronic structures and magnetic behaviours. Treatment of [U(Tren(TIPS))] [1, Tren(TIPS) = N(CH(2)CH(2)NSiPr(i) (3))(3)] with Ph(3)PS, selenium or tellurium...

Descripción completa

Detalles Bibliográficos
Autores principales: Gardner, Benedict M., King, David M., Tuna, Floriana, Wooles, Ashley J., Chilton, Nicholas F., Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5628351/
https://www.ncbi.nlm.nih.gov/pubmed/28989654
http://dx.doi.org/10.1039/c7sc01998j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5628351/
https://www.ncbi.nlm.nih.gov/pubmed/28989654
http://dx.doi.org/10.1039/c7sc01998j

Ejemplares similares